Search results for "Bridging oxygen"
showing 10 items of 14 documents
In situobservation of the formation, diffusion, and reactions of hydrogenous species inF2-laser-irradiatedSiO2glass using a pump-and-probe technique
2006
We quantitatively studied the formation, diffusion, and reactions of mobile interstitial hydrogen atoms $({\mathrm{H}}^{0})$ and molecules $({\mathrm{H}}_{2})$ in ${\mathrm{F}}_{2}$-laser-irradiated silica $(\mathrm{Si}{\mathrm{O}}_{2})$ glass between 10 and $330\phantom{\rule{0.3em}{0ex}}\mathrm{K}$. Two key techniques were used: single-pulse ${\mathrm{F}}_{2}$ laser photolysis of silanol (SiOH) groups to selectively create pairs of ${\mathrm{H}}^{0}$ and oxygen dangling bonds (nonbridging oxygen hole centers, NBOHC), and in situ photoluminescence measurements of NBOHCs to monitor their reactions with ${\mathrm{H}}^{0}$ and ${\mathrm{H}}_{2}$ as a function of time and temperature. A smalle…
Vibrational properties of the surface-nonbridging oxygen in silica nanoparticles
2008
By studying the site-selective luminescence spectra of oxidized silica nanoparticles we identify the electronic and the vibrational lines associated with the surface nonbridging oxygen, $\ensuremath{\equiv}{\text{Si-O}}^{\ifmmode\bullet\else\textbullet\fi{}}$. This defect emits a zero-phonon line inhomogeneously distributed around 2.0 eV with full width at half maximum of 0.04 eV, weakly coupled with the local ${\text{Si-O}}^{\ifmmode\bullet\else\textbullet\fi{}}$ stretching mode whose frequency is measured to be $920\text{ }{\text{cm}}^{\ensuremath{-}1}$. These findings are different from those of the well-characterized defect in the bulk silica thus evidencing structural peculiarities of …
Time Resolved Photoluminescence Associated with Non Bridging Oxygen Hole Centers in Irradiated Silica
2007
Interconversion between non-bridging oxygen hole center and peroxy radical in F2-laser-irradiated SiO2 glass
2004
Formation processes of the peroxy radical (POR) were examined in high-purity SiO 2 glass exposed to F 2 -laser light which creates mobile atomic oxygen (O 0 ) by photolyzing the interstitial oxygen molecules (O 2 ). It was proved that under these conditions POR is formed by a reaction of the non-bridging oxygen hole center (NBOHC, an oxygen dangling bond) with O 0 , not by a reaction between the E' center (a silicon dangling bond) and O 2 . Subsequent exposure to KrF laser light photolyzes POR and recoveres NBOHC by dissociating the O-O bond in POR. These findings corroborate the important role of O° in defect processes in SiO 2 glass.
Sodium Adsorption on the TiO2110 Surface an XAFS Structural Study
2005
The adsorption site of sodium atoms deposited onto a clean TiO2(110) surface has been determined by EXAFS. The best result is obtained for an 'in-between' site where the sodium is bound to two bridging oxygen atoms at 2.25 A and one in-plane one at 2.40 A in full agreement with DFT calculations. At higher coverage the site becomes a hollow site where Na is equidistant to the three oxygen atoms at 2.30 A.
Luminescence of the surface nonbridging oxygen hole center in silica: Spectral and decay properties
2008
We investigated the red luminescence in a porous film of silica nanoparticles, originating from surface nonbridging oxygen hole centers. The excitation spectrum was measured from 1.8 to 8.0 eV by a tunable laser system and a synchrotron radiation source; this spectrum evidences a peak at 2.0 eV, nearly overlapping with the emission, and an ultraviolet broadband with peaks at 4.8 and 6.0 eV. The emission is characterized by a spectrum with two subbands split by 0.07 eV, its decay occurs with lifetime longer than 30 microsec and undergoes a thermal quenching by a factor aboout 2 with increasing temperature from 10 to 290 K. The optical characteristics of surface and bulk centers are discussed…
Influence of fluorine on the fiber performance studied through the NBOHC-related 1.9 eV microluminescence
2012
International audience; The distribution of Non Bridging Oxygen Hole Centers (NBOHC) in Fluorine doped optical fibers was investigated by confocal microluminescence spectroscopy monitoring the characteristic 1.9 eV luminescence band. The results show that these defects are generated by the fiber drawing and their concentration further increases after γ irradiation. The NBOHC profile along the fiber is anticorrelated to the fluorine content. This finding agrees with the role of fluorine in the fiber toughness and is discussed from the microscopic point of view on the basis of previous works.